Journal of Electron Microscopy Advance Access originally published online on July 5, 2006
Journal of Electron Microscopy 2006 55(3):129-135; doi:10.1093/jmicro/dfl020
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Local lattice parameter determination of a silicon (001) layer grown on a sapphire (1
02) substrate using convergent-beam electron diffraction
1 Asahi-Kasei Co. Ltd, 2-1 Samejima Fuji 416-8501, Japan
2 Institute of Multidisciplinary Research for Advanced Materials, Tohoku University 2-1-1 Katahira Aoba-ku, Sendai 980-8577, Japan
*To whom correspondence should be addressed. E-mail: akaogi.tb{at}om.asahi-kasei.co.jp
All the six lattice parameters (a, b, c,
, ß and
) of a Si (001) layer grown on a sapphire (1
02) substrate were determined by convergent-beam electron diffraction with no assumption of crystal lattice symmetry. A lattice compression in the Si (001) plane and an elongation in the [001] direction were revealed. An anisotropic lattice compression in the (001) plane was clearly detected for the first time. That is, the lattice compression in the Si [100] direction, which is parallel to the sapphire [
101] direction, was larger than that of the Si [010] direction, which is parallel to the sapphire [
20] direction. It was also revealed that the lattice parameters of the Si-layer depend on the distance from the interface. Anisotropy of carrier mobility was reasonably explained in terms of the anisotropy of the lattice parameters determined.
Keywords lattice parameter determination, convergent-beam electron diffraction, lattice strain, SOS, Si on Sapphire, anisotropic lattice compression
Received 6 February 2006, accepted 8 June 2006